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The quasi Official "Stump Rilla Thread"

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  1. #151
    [quote="Greedo017"]What would you expect to be the major product formed when 2-pentanone is heated with benzaldehyde at 80 degrees in 5% NaOH solution.

    This is an aldol condensation reaction. The NaOH deprotonates one of the alpha hydrogens of the pentanone to form the enolate which then adds via nucleophilc attack to the highly electrophilic benzaldehyde to form the beta hydroxy intermediate which then (at 80 C) dehydrates to form the alph/beta ubnsaturated product (a substituted styrene big ugly iupac name which i am too lazy to look up). The tricky part of this is which alpha hydrogen gets deprotonated as there are three on the methyl of the pentanone and 2 on the alpha methylene. My guess is it is the kinetic product (due to the vigorous conditions) so the proton would e predominately from the methyl group. Am I right? Greed?
  2. #152
    Quote Originally Posted by boostNslide
    I just realized that my riddle is indeed flawed! If rilla can figure out how, then I will give him a star.
    You can not travel north on the north pole, every point is South, West, or east of every other point.
    If you put all your faith in the river, you are up shit's creek
  3. #153
    Quote Originally Posted by arkana
    Quote Originally Posted by Yeldud
    'Rilla actually hit the answer in his original post - to get the guy to come to the funeral. Even though there is no evidence to suggest he will, as his association could have been work, school, etc, the sister can only associate meeting him with a death event.

    The question actually came from a psychiatric evaluation I had to take as part of a job interview process.
    They were testing to see if you are a serial killer (I hope you didnt get the answer). I have heard of this question and apparently all serial killers get the answer instantly and since this was 'rillas first thought...
    I actually did get it right away - to be honest, I thought it was the pretty logical answer. After answering the woman administering the test told me that we would talk about the answer later. It was later that I found out that indeed if you answer it correctly in under one minute you have characteristics of a mind similar to that of serial killers.
    If you put all your faith in the river, you are up shit's creek
  4. #154
    Here is another question from the same test - worded differently, but you will get the jist. I did not answer this one correctly.

    A person puts your dick and balls in a vice, closes it, and welds it shut. They then put a sharp knife within your reaching distance and proceed to lite the buidling on fire. Do you cut them off and live; or die in the fire?

    Discuss.
    If you put all your faith in the river, you are up shit's creek
  5. #155
    Guest
    If you have it, you want to share it, but if you share it, you don't have it. What is it?
  6. #156
    a500lbgorilla's Avatar
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    Quote Originally Posted by arkana
    Quote Originally Posted by Yeldud
    'Rilla actually hit the answer in his original post - to get the guy to come to the funeral. Even though there is no evidence to suggest he will, as his association could have been work, school, etc, the sister can only associate meeting him with a death event.

    The question actually came from a psychiatric evaluation I had to take as part of a job interview process.
    They were testing to see if you are a serial killer (I hope you didnt get the answer). I have heard of this question and apparently all serial killers get the answer instantly and since this was 'rillas first thought...
    Heheheheh, oh fuck. Heh hahahahahah bwhahahahahahahah MUHAHAHAHAHAHAHAHAHAH MUHHAAHAAHAAHAAHAAHAA HAAHAAHAAHAAHAAHAAH

    Seriously?

    -'rilla
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  7. #157
    a500lbgorilla's Avatar
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    Quote Originally Posted by Yeldud
    Quote Originally Posted by arkana
    Quote Originally Posted by Yeldud
    'Rilla actually hit the answer in his original post - to get the guy to come to the funeral. Even though there is no evidence to suggest he will, as his association could have been work, school, etc, the sister can only associate meeting him with a death event.

    The question actually came from a psychiatric evaluation I had to take as part of a job interview process.
    They were testing to see if you are a serial killer (I hope you didnt get the answer). I have heard of this question and apparently all serial killers get the answer instantly and since this was 'rillas first thought...
    I actually did get it right away - to be honest, I thought it was the pretty logical answer. After answering the woman administering the test told me that we would talk about the answer later. It was later that I found out that indeed if you answer it correctly in under one minute you have characteristics of a mind similar to that of serial killers.
    Yah, that's wierd. It is the first thing that popped into my head becuase it made the most sense. And once it's in there, it's hard to get out (without mercilessly killing people).

    -'rilla
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  8. #158
    Quote Originally Posted by dwarfman
    If you have it, you want to share it, but if you share it, you don't have it. What is it?
    A secret - do I get a star now?
    If you put all your faith in the river, you are up shit's creek
  9. #159
    a500lbgorilla's Avatar
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    Quote Originally Posted by Yeldud
    Here is another question from the same test - worded differently, but you will get the jist. I did not answer this one correctly.

    A person puts your dick and balls in a vice, closes it, and welds it shut. They then put a sharp knife within your reaching distance and proceed to lite the buidling on fire. Do you cut them off and live; or die in the fire?

    Discuss.
    Assuming this isn't a trick involving knowledge of the vice or your ability to cut them off and not hit some major artery or survive the fire...

    Approaching this as a poker problem, which is greater EV, Dying or Living sans the General? It seems that living is the obvious answer.

    -'rilla
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  10. #160
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    Quote Originally Posted by Yeldud
    Quote Originally Posted by dwarfman
    If you have it, you want to share it, but if you share it, you don't have it. What is it?
    A secret - do I get a star now?
    No.

    You do however get a kick in the teeth for answering before giving 'Rilla a chance!
  11. #161
    a500lbgorilla's Avatar
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    Quote Originally Posted by dwarfman
    If you have it, you want to share it, but if you share it, you don't have it. What is it?
    STDs.

    "but if you share it, you don't have it."

    Queue Ron Mexico telling the chick he totally doesn't have Herpes.

    -'rilla
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  12. #162
    Quote Originally Posted by a500lbgorilla
    Quote Originally Posted by Yeldud
    Here is another question from the same test - worded differently, but you will get the jist. I did not answer this one correctly.

    A person puts your dick and balls in a vice, closes it, and welds it shut. They then put a sharp knife within your reaching distance and proceed to lite the buidling on fire. Do you cut them off and live; or die in the fire?

    Discuss.
    Assuming this isn't a trick involving knowledge of the vice or your ability to cut them off and not hit some major artery or survive the fire...

    Approaching this as a poker problem, which is greater EV, Dying or Living sans the General? It seems that living is the obvious answer.

    -'rilla
    Living is correct, but your reasoning is flawed. Hint - the "text book" answer has to do with your confidence - and nothing to do with vice knowledge or artery/vein knowledge.
    If you put all your faith in the river, you are up shit's creek
  13. #163
    a500lbgorilla's Avatar
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    Quote Originally Posted by Yeldud
    Quote Originally Posted by a500lbgorilla
    Quote Originally Posted by Yeldud
    Here is another question from the same test - worded differently, but you will get the jist. I did not answer this one correctly.

    A person puts your dick and balls in a vice, closes it, and welds it shut. They then put a sharp knife within your reaching distance and proceed to lite the buidling on fire. Do you cut them off and live; or die in the fire?

    Discuss.
    Assuming this isn't a trick involving knowledge of the vice or your ability to cut them off and not hit some major artery or survive the fire...

    Approaching this as a poker problem, which is greater EV, Dying or Living sans the General? It seems that living is the obvious answer.

    -'rilla
    Living is correct, but your reasoning is flawed. Hint - the "text book" answe rhas to do with your confidence.
    Without your boys, you won't live a confident life?

    I don't follow.

    -'rilla
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  14. #164
    Use the knife on a different locale.... you should be dead before the fire gets to you, which would be a horrible way to go IMHO. Though having your manhood clamped in a vise wouldn't be a picnic either.
    I built my own poker table... Check It Out
  15. #165
    did you say that this balls and knife one was actually from an interview too? that would be the weirdest interview question ever. Imagine if it was a hot chick interviewing you and she starts talking about your dick and balls...oh man interview over!
  16. #166
    Quote Originally Posted by a500lbgorilla
    Well, first I'll tell you why I feel its fine but not optimally worded.

    It says he stalks to bear but does not say in which direction. I assumed this meant you needed to focus on how a certain color bear moves. Like rivers flow south, this bear moves west. For it to truely be optimally worded, it would have needed to say that the bear moved X miles in X direction so that I would be forced to focus on the movement of the hunter north not as a constraint but as the riddle.

    -'rilla
    rilla, creative wording makes the riddle more fun. Its like those math problems back in 4th grade that had information that was not needed. Hell I coulda just said This guy walked south then west then north all equal distances and ended up in the same place, where is he? But thats not a fun riddle. And whether he walks off of his original path while stalking the bear or not doesnt matter. As long as he goes north he will end up back at his cabin.
  17. #167
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    I just realized that my riddle is indeed flawed! If rilla can figure out how, then I will give him a star.
    You can not travel north on the north pole, every point is South, West, or east of every other point.
    what in the hell are you talking about...
  18. #168
    michael1123's Avatar
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    Quote Originally Posted by Yeldud
    I actually did get it right away - to be honest, I thought it was the pretty logical answer. After answering the woman administering the test told me that we would talk about the answer later. It was later that I found out that indeed if you answer it correctly in under one minute you have characteristics of a mind similar to that of serial killers.
    Haha, that is very funny. Personally, that answer didn't enter my mind at all. I assumed that the man must've been married to his sister or something, and she found this out after the funeral. Or she killed her sister for some other reason (her sister inhereted all of her other sister's riches).

    I guess normal people think that killing your sister must require some great motive, while sickos like you and Rilla think that its a good way to meet people.
  19. #169
    !Luck's Avatar
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    I got a question. For how many pages will this thread go on?
  20. #170
    Quote Originally Posted by a500lbgorilla

    Yah, that's wierd. It is the first thing that popped into my head becuase it made the most sense. And once it's in there, it's hard to get out (without mercilessly killing people).

    -'rilla
    I think this deserves a black star
  21. #171
    Greedo017's Avatar
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    dalai, I actually got this question on my final (it was on an old test), and i got it wrong. i'll figure out the explanation sometime soon, my last final is today.
    i betcha that i got something you ain't got, that's called courage, it don't come from no liquor bottle, it ain't scotch
  22. #172
    It will probably go on for awhile as long as we stop discussin balls in a vice, not my fav topic

    Rilla, can you name me the four movies that actually shot footage inside of Fenway Park?


    Sox Fans' start learning at a very young age that the Yankee's Suck
  23. #173
    Quote Originally Posted by Grand_MasterB
    did you say that this balls and knife one was actually from an interview too? that would be the weirdest interview question ever. Imagine if it was a hot chick interviewing you and she starts talking about your dick and balls...oh man interview over!
    Yes it was (worded differently), it was part of a Psych. evaluation. The text book answer has nothing to do with using the knife or letting yourself get killed in the fire. The answer they were looking for is that you would never allow yourself to be in a position in which the General was in a vice.
    If you put all your faith in the river, you are up shit's creek
  24. #174
    Quote Originally Posted by boostNslide
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    I just realized that my riddle is indeed flawed! If rilla can figure out how, then I will give him a star.
    You can not travel north on the north pole, every point is South, West, or east of every other point.
    what in the hell are you talking about...
    So long as you are on the North Pole, you can not travel North - you are at the furthest point North. For example, if you build a house on the North Pole, all four walls technically point South. In your problem, you have the hunter walking "North" - which is not possible given their location.
    If you put all your faith in the river, you are up shit's creek
  25. #175
    a500lbgorilla's Avatar
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    Quote Originally Posted by !Luck
    I got a question. For how many pages will this thread go on?
    Six. If it threatens to go to seven, I'll lock it.

    -'rilla
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  26. #176
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    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    I just realized that my riddle is indeed flawed! If rilla can figure out how, then I will give him a star.
    You can not travel north on the north pole, every point is South, West, or east of every other point.
    what in the hell are you talking about...
    So long as you are on the North Pole, you can not travel North - you are at the furthest point North. For example, if you build a house on the North Pole, all four walls technically point South. In your problem, you have the hunter walking "North" - which is not possible given their location.
    the house is on the north pole, so when it says he is returning home he is going north.
  27. #177
    a500lbgorilla's Avatar
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    Quote Originally Posted by Wolverine42
    It will probably go on for awhile as long as we stop discussin balls in a vice, not my fav topic

    Rilla, can you name me the four movies that actually shot footage inside of Fenway Park?
    Fever Pitch and 3 others. :P

    -'rilla
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  28. #178
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    Quote Originally Posted by vaks
    Quote Originally Posted by Spook
    The answer to life, the universe, and everything?


    well duh...
    its 42
    thats fourty-two

    but heres the real stump... Whats the question?
    The question is:

    What's the Number for the building containing the club known as Stavro Mueller Beta?
    "We thought you was a toad!"
    -- O Brother Where Art Thou?
  29. #179
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    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    I just realized that my riddle is indeed flawed! If rilla can figure out how, then I will give him a star.
    You can not travel north on the north pole, every point is South, West, or east of every other point.
    what in the hell are you talking about...
    So long as you are on the North Pole, you can not travel North - you are at the furthest point North. For example, if you build a house on the North Pole, all four walls technically point South. In your problem, you have the hunter walking "North" - which is not possible given their location.
    In the riddle he travels "due South" first. Once he moves off the North Pole, he can again move North.

    (It's not totally clear what "due South" means when you're on the North Pole. I guess it is any direction at all.)
  30. #180
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    All of those riddles are very clever and keep your head warm in the cold, but this one is actually important, 'Rilla:

    What exactly is nog?

    And are there any other kinds of nog other than "egg"?

    Please be quick, as I have my balls in a vice and can't take them out until I know the answer.
  31. #181
    a500lbgorilla's Avatar
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    Quote Originally Posted by Zangief
    All of those riddles are very clever and keep your head warm in the cold, but this one is actually important, 'Rilla:

    What exactly is nog?

    And are there any other kinds of nog other than "egg"?

    Please be quick, as I have my balls in a vice and can't take them out until I know the answer.
    A nog in the sense of "eggnog" is a very strong ale of ye olde Britaine.

    Egg is the only "flavor" nog that I know of though.

    -'rilla
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  32. #182
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    Quote Originally Posted by a500lbgorilla
    Quote Originally Posted by Zangief
    All of those riddles are very clever and keep your head warm in the cold, but this one is actually important, 'Rilla:

    What exactly is nog?

    And are there any other kinds of nog other than "egg"?

    Please be quick, as I have my balls in a vice and can't take them out until I know the answer.
    A nog in the sense of "eggnog" is a very strong ale of ye olde Britaine.

    Egg is the only "flavor" nog that I know of though.

    -'rilla
    Thanks. Balls out of vice. Yay!
  33. #183
    a500lbgorilla's Avatar
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    Vices should have warnings on them!

    -'rilla
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  34. #184
    Sykedupp's Avatar
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    I got one for you rilla (and ONLY rilla)


    Give me MATHIMATICAL PROOF that girls are evil!

    :P

    -Chris
    Quote Originally Posted by soupie
    That is the beauty of poker, it doesnt matter how they play, you can always devise the perfect defense and counterpunch hard.
  35. #185
    !Luck's Avatar
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    Come on Skydupp that is too easy.
  36. #186
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    Quote Originally Posted by Sykedupp
    I got one for you rilla (and ONLY rilla)


    Give me MATHIMATICAL PROOF that girls are evil!

    :P

    -Chris
    I'm an engineer major, I see this joke on T-shirts all the time.

    But for those of you behind the learning curve, here it is:

    Girls require time and money,

    Girls = Time x Money

    Time is money, my friend.

    Time = Money

    Money is the root of all evil.

    Money = (Evil)^.5


    Girls = Time x Money
    Girls = Money x Money
    Girls = (Money)^2
    Girls = ((Evil)^.5)^2)
    Girls = Evil

    Further refined:

    Taking square of the sqrt of any non imagninary number will yield a non-negative value or the absolute value.

    Girls = ((Evil)^.5)^2
    Girls = |Evil|

    So, when not dealing in some imaginary plane, Girls are absolute evil.

    -'rilla
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  37. #187
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    I just realized that my riddle is indeed flawed! If rilla can figure out how, then I will give him a star.
    You can not travel north on the north pole, every point is South, West, or east of every other point.
    what in the hell are you talking about...
    So long as you are on the North Pole, you can not travel North - you are at the furthest point North. For example, if you build a house on the North Pole, all four walls technically point South. In your problem, you have the hunter walking "North" - which is not possible given their location.
    please reread the riddle, at no point does the hunter travel north while at the north pole.
  38. #188
    Quote Originally Posted by Zangief
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    I just realized that my riddle is indeed flawed! If rilla can figure out how, then I will give him a star.
    You can not travel north on the north pole, every point is South, West, or east of every other point.
    what in the hell are you talking about...
    So long as you are on the North Pole, you can not travel North - you are at the furthest point North. For example, if you build a house on the North Pole, all four walls technically point South. In your problem, you have the hunter walking "North" - which is not possible given their location.
    In the riddle he travels "due South" first. Once he moves off the North Pole, he can again move North.

    (It's not totally clear what "due South" means when you're on the North Pole. I guess it is any direction at all.)
    In what way is it relevant which "south" he goes?
  39. #189
    Guest
    Quote Originally Posted by boostNslide
    Quote Originally Posted by Zangief
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    Quote Originally Posted by Yeldud
    Quote Originally Posted by boostNslide
    I just realized that my riddle is indeed flawed! If rilla can figure out how, then I will give him a star.
    You can not travel north on the north pole, every point is South, West, or east of every other point.
    what in the hell are you talking about...
    So long as you are on the North Pole, you can not travel North - you are at the furthest point North. For example, if you build a house on the North Pole, all four walls technically point South. In your problem, you have the hunter walking "North" - which is not possible given their location.
    In the riddle he travels "due South" first. Once he moves off the North Pole, he can again move North.

    (It's not totally clear what "due South" means when you're on the North Pole. I guess it is any direction at all.)
    In what way is it relevant which "south" he goes?
    Moving off topic *slightly*, what an incredibly large quoting tree!

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