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Your calcs are wrong. First calculate how often you will NOT make a pair by the river (assuming your opponent's cards are unknown). There are 50 unknown cards out there, and 44 of them are non A or Q.
- probability of not pairing on the first board card: 44/50
- probability of not pairing on the second board card knowing that you did not pair on the first board card: 43/49
- probability of not pairing on the third board card knowing that you did not pair on the first two board cards: 42/48
- 4th board card: 41/47
- 5th board card: 40/46
Probability of all these events happening: 44/50*43/49*42/48*41/47*40/46=51.25%
So the probability that you do NOT make a pair by the river is 51.25%, and so the probability that you DO make a pair by the river is 100-51.25=48.75%
Your opponent has the same odds of making a pair with his 83o.
So now, how can he win?
1) mostly, if you do not make a pair and he does make at least a pair
2) sometimes, if you do make a pair, but he does make two pairs, trips, a straight or a flush and you do not
1) How often does he NOT make a pair knowing that you do not either and you hold AQ? There are 36 non 8 or 3 cards in the 42 cards deck (we removed all the A and Q and one 8 and one 3 from the 52 cards deck), so again:
- chance of not pairing on the first board card: 36/42
- second board card, knowing the first one did not pair: 35/41
- etc
- so the probability he does not make a pair or better when you do not is 36/42*35/41*34/40*33/39*32/38=44%
- so the probability he does make a pair or better knowing that you do not is 100-44=56%
- so the probability he wins like this is 0.4875*0.56=27.3%
2) This is vastly more complicated to calculate, but we can see it does not happen all that often, so we will just give it a few %, say around 5%. You can check this with Pokerstove: run AQo vs 83o on a board that has a single As card: you find that 83o has about 9% chance to win. Since your chance to make a pair is 51.75%, the chance that you make a pair and he wins is about 0.09*0.5175=4.7%
27.3% + 4.7% = 32%
Headache yet? use Pokerstove
It is also useful to know by heart the rough odds of common preflop all in hands, especially when playing all in or fold game in tournaments. For example high pocket pair vs low pocket pair ~ 80/20, pocket pair vs two higher cards ~ 52/48, etc.
Wanna learn the math? Read Sklansky's "No Limit Theory and Practice", and read the posts by Spoonitnow on this board. Lots of good links here:
http://www.flopturnriver.com/pokerfo...ds-186705.html
and here:
http://www.flopturnriver.com/pokerfo...re-123008.html
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