Great post, this has really clarified a lot for me. Of course it will take a while to absorb it.
I'm having a little trouble with this paragraph:
If we hold A4s, then there are now only 96 hand combinations that make up {22+, AQ+} since we're taking away 3 possibilities each for AA and 44, and 4 possibilities each for AQ and AK. Villain continues with {QQ+, AK}, which is now only 27 combinations. This means that when we hold A5s, Villain continues just 28.1% of the time, and folds 71.9% of the time.
Surely it is 104-14 = 90 combinations?
Also, we are holding A4s not A5s or am I missing something

I don't mean to nitpick but for a newbie I'm always worried I have misunderstood or missed something that I should be aware of.
Also, you made an offer for people to send you an e-mail with specific questions. Is that still open and if so does it apply to any questions we may have?