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Here's how to think of it ... there are 52 positions in the deck ... so there are 52 places the first q can be in ... after that is chosen, there are 51 other places the next can be in, 50 for the 3rd q and 49 for the 4th. So there are 52*51*50*49 different arrangements of places for the 4 queens to be in. Since we don't care about particular queens' positions, we divide by 4*3*2*1 or the 24 different ways you can arrange 4 queens.
It's the same with the 25 cards that are dealt.
This is an interesting question, but you should realize it gives you no information on how to play a particular hand. If you are in a hand, you have information, and therefore must calculate conditional probabilities. For example, you have Q2 and the flop comes with 2 queens. What is the probability someone else got dealt a Q? This is useful because if someone else has the q you are almost certainly outkicked. Turns out that probability is very simple, its 18/47. There are 18 places the queen could be among your opponents' hands and 47 places it could be among the cards you haven't seen.
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